CartaMundi told me these will never be produced in high volume like the lower denoms, even though they are the only ones that actually figure in the movie itself.
Theyve reserved them for limited edition sets with a small number of each denom in each set only. I dont know the makeup of the sets yet.
I have two sets to sell and I need $30 shipped per set. Email me if interested.

For the record they are not film props, they are remanufactured but are just about identical.
The top 3 chips in the scan are the type Im selling.
The bottom 3, not for sale, are the props. From the scan its almost impossible to see the difference. Only thing I can say is the props have perfect bevelled edges (only place you can see on scan is bottom of the middle chip) and are a bit more polished. Also, the remakes are perfectly medal aligned. The props are not aligned at all.
For those that dont know, the props (or a vast majority) were given away with 'invites' to premieres, first showings, VIPs etc and with some LE model car sets.
I was lucky enough to get mine back in October from someone involved in the marketing of the Casino Royale products, together with a 'marketing guide' and 'premiere invite'.
Shame I got the invite 3 weeks after the premiere